정보 | Shear Rate’s Critical Role in Polymer Melt Integrity
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작성자 Glenn Pickrell 작성일25-12-22 10:11 조회7회 댓글0건본문
The quality of a polymer melt is directly governed by the shear rate applied during processing. Shear rate refers to the rate at which layers of the polymer flow past one another, and it plays a pivotal role in defining the final properties of the formed part. At low shear rates, the polymer chains have ample opportunity to relax and align slowly, which can lead to uneven flow and poor homogeneity. This often results in surface defects such as sharkskin or melt fracture, particularly in long-chain thermoplastics.
As the shear rate increases, the polymer chains begin to orient along the flow, which can boost the uniformity of the melt and تولید کننده کامپاند پلیمری lower viscosity. This non-Newtonian response is advantageous in many processing applications because it facilitates enhanced flow through dies and molds while avoiding excessive pressure. However, if the shear rate becomes overly intense, the polymer chains can be strained beyond capacity or even broken down. This leads to molecular weight reduction, which weakens the mechanical properties of the final product.
Excessive shear can also produce concentrated thermal energy due to viscous dissipation, causing thermal degradation in temperature-vulnerable materials. This can result in color changes, unpleasant smells, or the generation of volatile byproducts that compromise product integrity. In addition, high shear rates may cause non-uniform velocity profiles, leading to residual strain that appear as warping or shape distortion after cooling.
To achieve optimal melt quality, processors must carefully balance the shear rate with the polymer’s viscoelastic behavior, melt temperature, and tooling parameters. Using the appropriate screw geometry, zoned heating settings, and die design helps ensure a consistent and moderate shear rate throughout the process. Monitoring and controlling shear rate ensures that the polymer melt remains predictable, even, and intact, ultimately producing parts with uniform quality and flawless appearance.
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